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Vyalsovite

Collectors Summary

Color karminrot-met.
Crystal System orthorhombisch,

Chemism

Chemical formula

FeS·Ca(OH)2·Al(OH)3

Chemical composition

Aluminium, Calcium, Eisen, Sauerstoff, Schwefel, Wasserstoff

Unit weight: 240.0075232 u; Number of atoms in the formula: 14

Info

Empirical formula:

FeS·Ca(OH)2·Al(OH)3

Element

Symbol

Weight%

Atoms

Atoms%

Atom weight (u)

Sum weight (u)

Hydrogen

H

2.10

5

35.71

1.0079470

5.0397350

Oxygen

O

33.33

5

35.71

15.9994300

79.9971500

Aluminium

Al

11.24

1

7.14

26.9815382

26.9815382

Sulfur

S

13.36

1

7.14

32.0655000

32.0655000

Calcium

Ca

16.70

1

7.14

40.0784000

40.0784000

Iron

Fe

23.27

1

7.14

55.8452000

55.8452000

Strunz 9th edition incl. updates

2.FD.45

2: Sulfide und Sulfosalze (Sulfide, Selenide, Telluride, Arsenide, Antimonide, Bismutide, Sulfoarsenide, Sulfoantimonide, Sulfobismuthide)
F: Sulfide, Arsenide, Alkaide; Sulfide mit Halogeniden, Oxiden, Hydroxiden (H2O)
D: mit O, OH, H2O
45:Vyalsovit-Gruppe

Lapis Classification

II/C.23-050

II: SULFIDE UND SULFOSALZE (Sulfide, Selenide, Telluride, Arsenide, Antimonide, Bismutide)
C: Sulfide mit Metall : S,Se,Te ~ 1:1

Classification by Hölzel

2.KC.280

2: SULFIDES
K: Nonmetallic Sulfides, HalideSulfides, etc.
C: With O,OH,H2O
2: With Hydroxide

Dana 8th edition

02.14.04.01

02: Sulfide Minerals
14: Sulfides - Including Selenides and Tellurides (Hydroxyl or Hydrated)

IMA status

Anerkannt von der CNMNC

Mineral status

anerkanntes Mineral

Optical Properties

Color

karminrot-met.

Crystallography

Crystal System

orthorhombisch

Cell parameters a (Å)

14.20

Cell parameters b (Å)

20.98

Cell parameters c (Å)

5.496

Cell parameters a/b or c/a

0.677

Cell parameters c/b

0.262

Cell parameters α

90°

Cell parameters β

90°

Cell parameters γ

90°

Z

8

Volume (ų)

1637.346

Crystal structure

aufgeklärt, Soboleva, S.V., Boeva, N.M., Evstigneeva, T.E. et al.: The Crystal Structure of Vyalsovite FeCаAlS(OH)5: First Example of the Commensurate Combination of Iron Sulfide and Hydroxide Layers. Dokl. Earth Sc. Vol. 503 (2022) S. 164–167. https://doi.org/10.1134/S1028334X22040171

X-Ray Powder Diffraction

5.40(100),
4.76(40),
2.88(20),
2.16(50),
1.973(30),
1.894(30),
1.846(30),
1.676(40)

XRD chart Vyalsovite

Calculated from d-spacing and intensity at 0.1541838 nm (Cu)

Physical Properties

Density (g/cm³)

1.96 (errechnet)

1.947 ( ρ calc. Mineralienatlas )

Preface

Occurrences

Forsteritskarne zusammen mit nichtsulfidischen Mineralien und Sulfiden.

Associations

Spinell, Magnetit, Diaspor, Forsterit, Chalkopyrit, Pentlandit, Valleriit, Pyrit, Djerfisherit, Serpentin

Name from

Leonid N. Vyalsov

Author (Name, Year)

Evstigneeva & Genkin & Sandomirskaya & Trubkin, 1992

References

American Mineralogist 77 (1992), 201

Other languages

German

Vyalsovit

Spanish

Vyalsovita

English

Vyalsovite

French

Vyalsovite

Russian

Вяльсовит

CNMNC (IMA)-Number

IMA 1989-004

CNMNC symbol

Symbol

Vyl

Locations with GPS information

IDs

GUSID (Global unique identifier short form) qC_kGUjeOEal4ROQmad-Ew
GUID (Global unique identifier) 19E42FA8-DE48-4638-A5E1-139099A77E13
Database ID 4097